Just loading the sysctl values will not switch the packet scheduler on already existing network interfaces, but it will start using BBR on new sockets.
Switching the scheduler at runtime using tc qdisc replace is possible, but then you need to take extra care if the device is multi queue or not. Instead of explaining it all here just rebooting is probably simpler.
CONFIG_TCP_CONG_BBR
CONFIG_NET_SCH_FQ (not to be confused with FQ_CODEL)
Put these into /etc/sysctl.conf:
net.core.default_qdisc=fq
net.ipv4.tcp_congestion_control=bbr
Reboot.